… Various reaction conditions have been discovered and … Instead, most radical reactions have
innate chains which form … and catalytic radical reactions through the lens of radical chemistry…

… radical polarity in radical reactions. An important problem that needs to be faced when using
radical reactions … Thus, an adjacent chiral centre can influence the radical reaction leading …

For many years, free radical species have been known to be intermediates in a large number
of chemical reactions and have been credited to produce polymers of industrial importance…

… bulk radical reactions with reasonable rate constants. The operation of the effect should
cause rather large concentrations of the ketyl radical species, and these are in fact observed. …

… RECENT work in this laboratory and elsewherel has demonstrated that thermochemical
criteria, although widely employed for the prediction or rationalisation of the results of free-radical …

… radical reactions and the guidelines that are helpful to apply them. We will suggest repeatedly
that stereoselective radical reactions … structure and reactivity of radicals. We will illustrate …

… The regio- and chemoselectivities of free radical reactions are often high and largely … radical
reactions can also be directed. Examples involving five- and six-membered cyclic radicals …

… Our first carbon−carbon bond forming free radical reaction that proceeded with high … the
reaction of radicals substituted α to an oxazolidinone. Thus, the addition of alkyl radicals to …

… of radical reactions in natural product synthesis. By summarizing accomplishments of the last
decade, we hope to further expose the unique features of radical reactions … reactions, nor is …

… with the chemistryand biology offree radical reactions; we, therefore, only wishto review …
free radical reactions. These arethe antioxidants interferingwith the reactions offree radical …