Recent advances in theoretical liquid crystal rheology

AD Rey, T Tsuji - Macromolecular theory and simulations, 1998 - Wiley Online Library
AD Rey, T Tsuji
Macromolecular theory and simulations, 1998Wiley Online Library
Recent significant advances in theoretical liquid crystalline rheology are presented.
Dynamic simulations are performed using a complete theory which include the three major
effects of liquid crystalline materials:(1) short range order elasticity,(2) long range order
elasticity, and (3) viscous flow effects. The results and discussions include rectilinear simple
shear flow, complex non‐linear phenomena such as defect texture generation and
coarsening processes under quiescent and shear conditions, and pattern formation such as …
Abstract
Recent significant advances in theoretical liquid crystalline rheology are presented. Dynamic simulations are performed using a complete theory which include the three major effects of liquid crystalline materials: (1) short range order elasticity, (2) long range order elasticity, and (3) viscous flow effects. The results and discussions include rectilinear simple shear flow, complex non‐linear phenomena such as defect texture generation and coarsening processes under quiescent and shear conditions, and pattern formation such as banded texture during and after cessation of flow. The complete theory predicts four in‐plane (1‐D orientation) flow modes and five out‐of‐plane (2‐D orientation) flow modes in one‐dimensional shear flow, depending on the magnitudes of R (ratio of short to long range order elasticity) and Er (Ericksen number: ratio of viscous to elastic force). The multistability of these flow modes is clearly explained in terms of degrees of freedoms in the nematic orientation. The number of degrees of freedom increases with increasing the spatial dimension of the system, and thus more complex orientation patterns arise in the higher dimension. Well‐known defect structures arise and coarsen during simulations of the isotropic to nematic phase transition. The effect of shear flow on the defect generation process is to suppress the defect nucleation, and the simulations suggest a method of how to create defect‐free nematic samples. The banded textures during and after cessation of flow are also captured by the complete theory.
Wiley Online Library
以上显示的是最相近的搜索结果。 查看全部搜索结果