metal ions in some metal‐hyperaccumulating plants.• Closely‐related nickel (Ni)‐and zinc
(Zn)‐hyperaccumulating species were studied to determine whether a correlation exists
between the Ni and Zn concentrations and NA in foliar tissues.• A liquid chromatography–
mass spectrometry (LC‐MS) procedure was developed to quantify the NA and amino acid
contents using the derivatizing agent 6‐aminoquinolyl‐N‐hydroxysuccinimidyl carbamate. A …