Removal of hydrogen sulfide from coke oven gas by catalytic oxidative absorption in a rotating packed bed

H Zou, M Sheng, X Sun, Z Ding, M Arowo, Y Luo… - Fuel, 2017 - Elsevier
H Zou, M Sheng, X Sun, Z Ding, M Arowo, Y Luo, L Zhang, G Chu, JF Chen, B Sun
Fuel, 2017Elsevier
The shortage of low-sulfur coking coal will bring about an increasingly high hydrogen sulfide
(H 2 S) in the coke oven gas (COG) in the near future. This work investigated the removal of
hydrogen sulfide (H 2 S) from a simulated coke oven gas (COG) by catalytic oxidative
absorption in a rotating packed bed (RPB). Sodium carbonate (Na 2 CO 3) solution doped
with 20 mg L− 1 of a commercial “888” catalyst was used as the absorbent. The removal
efficiency of H 2 S was evaluated under various operating conditions including rotation …
The shortage of low-sulfur coking coal will bring about an increasingly high hydrogen sulfide (H 2 S) in the coke oven gas (COG) in the near future. This work investigated the removal of hydrogen sulfide (H 2 S) from a simulated coke oven gas (COG) by catalytic oxidative absorption in a rotating packed bed (RPB). Sodium carbonate (Na 2 CO 3) solution doped with 20 mg L− 1 of a commercial “888” catalyst was used as the absorbent. The removal efficiency of H 2 S was evaluated under various operating conditions including rotation speed of the RPB (N), liquid-gas ratio (L/G), inlet H 2 S concentration (c H 2 S, in), temperature (T) and Na 2 CO 3 concentration (c Na 2 CO 3) in an attempt to optimize the conditions. The results were validated by comparison with those of separate experiments conducted in a packed column comprising a high-efficiency laboratory packing of Dixon rings. The comparison results reveal that the RPB exhibited higher H 2 S removal efficiency than the packed column, indicating it as an efficient gas-liquid contactor with a greater potential to remove H 2 S from COG.
Elsevier
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