[PDF][PDF] Ring-opening of oxiranes using Taeniolite-supported tris (β-diketonato) zirconium
Y Permana, N Ichikuni, S Shimazu - ITB Journal of Science, 2012 - researchgate.net
Y Permana, N Ichikuni, S Shimazu
ITB Journal of Science, 2012•researchgate.netA series of tris (β-diketonato) zirconium (IV) complexes were immobilized into a synthetic
clay structure of Taeniolite by an ion-exchange method to generate organic/inorganic hybrid
compounds. The hybrid compound served as a good catalyst for ring-opening reactions of
methyl, ethyl, and dimethyl oxiranes with various alcohols to generate primary alkoxy
alcohols in appreciable selectivity. This method described a technique to immobilize cationic
zirconium complexes without losing selectivity.
clay structure of Taeniolite by an ion-exchange method to generate organic/inorganic hybrid
compounds. The hybrid compound served as a good catalyst for ring-opening reactions of
methyl, ethyl, and dimethyl oxiranes with various alcohols to generate primary alkoxy
alcohols in appreciable selectivity. This method described a technique to immobilize cationic
zirconium complexes without losing selectivity.
Abstract
A series of tris (β-diketonato) zirconium (IV) complexes were immobilized into a synthetic clay structure of Taeniolite by an ion-exchange method to generate organic/inorganic hybrid compounds. The hybrid compound served as a good catalyst for ring-opening reactions of methyl, ethyl, and dimethyl oxiranes with various alcohols to generate primary alkoxy alcohols in appreciable selectivity. This method described a technique to immobilize cationic zirconium complexes without losing selectivity.
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