Role of different counterions and size of micelle in concentration dependence micellar structure of ionic surfactants

VK Aswal, PS Goyal - Chemical physics letters, 2003 - Elsevier
Small-angle neutron scattering experiments have been carried out on aqueous micellar
solutions of cationic surfactants cetyltrimethylammonium bromide (CTABr),
cetyltrimethylammonium chloride (CTACl) and dodecyltrimethylammoinum bromide (DTABr)
as a function of varying surfactant concentration. It is found that while CTABr shows sphere-
to-rodlike transition of micelles with the increase in the surfactant concentration, the micelles
of CTACl and DTABr remain more or less spherical even at very high surfactant …
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