Sensitive Deep Ultraviolet Photodetector and Image Sensor Composed of Inorganic Lead-Free Cs3Cu2I5 Perovskite with Wide Bandgap

ZX Zhang, C Li, Y Lu, XW Tong, FX Liang… - The journal of …, 2019 - ACS Publications
The journal of physical chemistry letters, 2019ACS Publications
In this work, a sensitive deep ultraviolet (DUV) light photodetector based on inorganic and
lead-free Cs3Cu2I5 crystalline film derived by a solution method was reported.
Optoelectronic characterization revealed that the perovskite device exhibited nearly no
sensitivity to visible illumination with wavelength of 405 nm but exhibited pronounced
sensitivity to both DUV and UV light illumination with response speeds of 26.2/49.9 ms for
rise/fall time. The I light/I dark ratio could reach 127. What is more, the responsivity and …
In this work, a sensitive deep ultraviolet (DUV) light photodetector based on inorganic and lead-free Cs3Cu2I5 crystalline film derived by a solution method was reported. Optoelectronic characterization revealed that the perovskite device exhibited nearly no sensitivity to visible illumination with wavelength of 405 nm but exhibited pronounced sensitivity to both DUV and UV light illumination with response speeds of 26.2/49.9 ms for rise/fall time. The Ilight/Idark ratio could reach 127. What is more, the responsivity and specific detectivity were calculated to be 64.9 mA W–1 and 6.9 × 1011 Jones, respectively. In addition, the device could keep its photoresponsivity after storage in air environment for a month. It is also found that the capability of Cs3Cu2I5 crystalline film device can readily record still DUV image with acceptable resolution. The above results confirm that the DUV photodetector may hold great potential for future DUV optoelectronic device and systems.
ACS Publications
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