Various configurations of power-to-gas system are investigated as a means for capturing excess wind power in the Emden region of Germany and transferring it to the natural gas grid or local biogas-CHP plant. Consideration is given to producing and injecting low concentration hydrogen admixtures, synthetic methane, or hydrogen/synthetic methane mixtures. Predictions based on time series data for wind generation and electricity demand indicate that excess renewable electricity levels will reach about 40 MW and 45 GW h per annum by 2020, and that it is desirable to achieve a progression in power-to-gas capacity in the preceding period. The findings are indicative for regions transitioning from medium to high renewable power penetrations. To capture an increasing proportion of the growing amount of excess renewable electricity, the following recommendations are made: implement a 4 MW hydrogen admixture plant and hydrogen buffer of 600 kg in 2018; then in 2020, implement a 17 MW hybrid system for injecting hydrogen and synthetic methane (with a hydrogen storage capacity of at least 400 kg) in conjunction with a bio-methane injection plant. The 17 MW plant will capture 68% of the available excess renewable electricity in 2020, by offering an availability to the electricity grid operator of >97% and contributing 19.1 GW h of ‘green’ gas to the gas grid.