RF energy harvesting (RFH) is emerging as a potential method for the proactive energy replenishment of next generation wireless networks. Unlike other harvesting techniques that depend on the environment, RFH can be predictable or on demand, and as such it is better suited for supporting quality-of-service-based applications. However, RFH efficiency is scarce due to low RF-to-DC conversion efficiency and receiver sensitivity. In this article, we identify the novel communication techniques that enable and enhance the usefulness of RFH. Backed by some experimental observations on RFH and the current state of the art, we discuss the challenges in the actual feasibility of RFH communications, new research directions, and the obstacles to their practical implementation.