Static and dynamic correlation lengths in supercooled polymers

C Balbuena, MM Gianetti, ER Soulé - The Journal of Chemical Physics, 2019 - pubs.aip.org
A key point to understand the glass transition is the relationship between structural and
dynamic behavior experienced by a glass former when it approaches T g. In this work, the
relaxation in a simple bead-spring polymer system in the supercooled regime near its glass
transition temperature was investigated with molecular dynamic simulations. We develop a
new manner to look at the dynamic length scales in a supercooled polymeric system,
focusing on correlated motion of particles in an isoconfigurational ensemble (that is …
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