Structural, photophysical, and electrochemical properties of doubly fused porphyrins and related fused chlorins
The electrochemical and physicochemical properties of tetraphenylporphyrins and
tetraphenylchlorins with two fused indanedione (IND) or malononitrile (MN) groups and two
antipodal Br, Ph, or H β-substituents are investigated in nonaqueous media. These
compounds were synthesized by oxidative fusion of free-base trans-chlorins, followed by
metalation. The corresponding free-base di-fused chlorins were also isolated as
intermediates and characterized for comparisons. The examined di-fused porphyrins (DFP) …
tetraphenylchlorins with two fused indanedione (IND) or malononitrile (MN) groups and two
antipodal Br, Ph, or H β-substituents are investigated in nonaqueous media. These
compounds were synthesized by oxidative fusion of free-base trans-chlorins, followed by
metalation. The corresponding free-base di-fused chlorins were also isolated as
intermediates and characterized for comparisons. The examined di-fused porphyrins (DFP) …
Structural, Photophysical, and Electrochemical Properties of Doubly Fused Porphyrins and Related Fused Chlorins
N Grover - 2019 - dspace.bits-pilani.ac.in
The electrochemical and physicochemical properties of tetraphenylporphyrins and
tetraphenylchlorins with two fused indanedione (IND) or malononitrile (MN) groups and two
antipodal Br, Ph, or H β-substituents are investigated in nonaqueous media. These
compounds were synthesized by oxidative fusion of free-base trans-chlorins, followed by
metalation. The corresponding free-base di-fused chlorins were also isolated as
intermediates and characterized for comparisons. The examined di-fused porphyrins (DFP) …
tetraphenylchlorins with two fused indanedione (IND) or malononitrile (MN) groups and two
antipodal Br, Ph, or H β-substituents are investigated in nonaqueous media. These
compounds were synthesized by oxidative fusion of free-base trans-chlorins, followed by
metalation. The corresponding free-base di-fused chlorins were also isolated as
intermediates and characterized for comparisons. The examined di-fused porphyrins (DFP) …
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