… ,4 5thus making its structural determination one of the most exciting challenges innatural
products chemistry. We previously reported partial structures of MTX5(fragments A and C) and …

… of the structure of the largest known natural product that is not a biopolymer (maitotoxin)
has … In the contracted structure below, the acyclic side chains are attached to the termini of a …

… structure of maitotoxin … structure ofMTX comprisesa C142 carbon chain encompassing 32
ether rings, 28 hydroxyl groups, and two sulfate esters. In this paper, we report the structure of …

… structural targets in natural product chemistry. Despite our efforts to elucidate the structure of
… In this communication, we wish to report a partial structure of MTX (1) which accounts for 30…

… Marine natural products such as okadaic acid, brevetoxins, ciguatoxin, palytoxin and
maitotoxin attract considerable attention among not only natural product chemists but also …

… of the structure of the largest known natural product that is not a biopolymer (maitotoxin)
has … In the contracted structure below, the acyclic side chains are attached to the termini of a …

… maitotoxin, is a 3422 Da polyketide-derived polycyclic ether isolated from the marine
dinoflagellate, Gambierdiscus toxicus.[1] The structure of maitotoxin … construct the maitotoxin …

… Fully assigned by 1996, the structure of this … over the structure of maitotoxin that prompted
us to study this molecule. Our initial inquiry was directed toward the true structure of maitotoxin, …

By addressing the relative stereochemistry of the four acyclic portions via organic synthesis,
the complete relative stereochemistry of maitotoxin (MTX) has been established as 1B. The …

… This approach is then extended to the case of the marine natural product maitotoxin. …
However, we realized that the information given by the gross structure was not sufficient …