Study of UV-aging of thermoplastic polyurethane material

A Boubakri, N Guermazi, K Elleuch, HF Ayedi - Materials Science and …, 2010 - Elsevier
A Boubakri, N Guermazi, K Elleuch, HF Ayedi
Materials Science and Engineering: A, 2010Elsevier
In the present work, the characteristics of thermoplastic polyurethane (TPU) material
exposed to artificial weathering environment for different durations were studied. The
influence on (i) appearance and morphology,(ii) thermal properties and (iii) mechanical
properties evolution of the material were investigated during aging. For this purpose,
ultraviolet (UV) chamber was used as accelerated aging technique. Optical and scanning
electron microscopy (SEM) observations revealed changes in appearance and morphology …
In the present work, the characteristics of thermoplastic polyurethane (TPU) material exposed to artificial weathering environment for different durations were studied. The influence on (i) appearance and morphology, (ii) thermal properties and (iii) mechanical properties evolution of the material were investigated during aging. For this purpose, ultraviolet (UV) chamber was used as accelerated aging technique. Optical and scanning electron microscopy (SEM) observations revealed changes in appearance and morphology of TPU material after UV-exposure. From differential scanning calorimetry (DSC) analysis, it was mainly found that thermal properties, in terms of glass transition temperature (Tg), were affected. Changes in mechanical behaviour were equally discerned using both computer-controlled tensile testing and abrasive wear tester. The mechanical properties in bulk of the studied material displayed tow steps. The elastic modulus and the stress at 200% of strain initially decreased and then increased progressively revealing an increase in crosslink density. The tribological properties, in terms of wear resistance, were affected and this degradation became more important with UV-exposure. Furthermore, our experimental results displayed prominently that there was a competition between chain scission and crosslinking mechanisms.
Elsevier
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