Study on δ‐form complex in a syndiotactic polystyrene/organic molecules system, 1. Preferential complexing behavior of xylene isomers

M Sivakumar, Y Yamamoto… - Macromolecular …, 2002 - Wiley Online Library
M Sivakumar, Y Yamamoto, D Amutharani, Y Tsujita, H Yoshimizu, T Kinoshita
Macromolecular rapid communications, 2002Wiley Online Library
To investigate the preferential complexing behavior of isomeric xylenes, syndiotactic
polystyrene (sPS) membranes are prepared using varying compositions of m‐and p‐xylene.
Complex formation between sPS and the xylenes was studied by means of
thermogravimetric and FT‐IR analyses to determine the exact amounts of solvent molecules
present per styrene repeating unit. A preferential complexing ability of p‐xylene was
revealed due to its favorable interaction with sPS.
Abstract
To investigate the preferential complexing behavior of isomeric xylenes, syndiotactic polystyrene (sPS) membranes are prepared using varying compositions of m‐ and p‐xylene. Complex formation between sPS and the xylenes was studied by means of thermogravimetric and FT‐IR analyses to determine the exact amounts of solvent molecules present per styrene repeating unit. A preferential complexing ability of p‐xylene was revealed due to its favorable interaction with sPS.
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