Sumanene derivatives functionalized at the internal carbon
N Ngamsomprasert, JS Dang… - Chemical …, 2017 - pubs.rsc.org
N Ngamsomprasert, JS Dang, S Higashibayashi, Y Yakiyama, H Sakurai
Chemical Communications, 2017•pubs.rsc.org… This reaction demonstrated another derivatization approach of buckybowls, which
prepares the buckybowl derivatives that are tethered to the convex internal position, unlike
in fullerene chemistry. In this communication, we report that the syntheses of the first
sumanene derivatives tethered by a hydroxy or methoxy group at the convex internal
carbons, together with their crystal structures, chirality, and photophysical properties. … In
conclusion, we succeeded in the functionalization at the internal carbon of …
prepares the buckybowl derivatives that are tethered to the convex internal position, unlike
in fullerene chemistry. In this communication, we report that the syntheses of the first
sumanene derivatives tethered by a hydroxy or methoxy group at the convex internal
carbons, together with their crystal structures, chirality, and photophysical properties. … In
conclusion, we succeeded in the functionalization at the internal carbon of …
The first sumanene derivatives functionalized at the convex face of the internal carbon were reported. The structure of racemic hydroxysumanenone was confirmed by X-ray crystal analysis. The obtained structure was composed of the single enantiomer.
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