Supersonically Sprayed Zn2SnO4/SnO2/CNT Nanocomposites for High-Performance Supercapacitor Electrodes

E Samuel, TG Kim, CW Park, B Joshi… - ACS Sustainable …, 2019 - ACS Publications
ACS Sustainable Chemistry & Engineering, 2019ACS Publications
In this study, we demonstrate rapid and facile supersonic cold spray deposition of
Zn2SnO4/SnO2/CNT nanocomposite supercapacitor electrodes with promising
combinations of power and energy density. Cyclic voltammetry confirmed the capacitive
behavior of the optimized electrode, with specific capacitance reaching 260 F· g–1 at a
current density of 10 A· g–1. We attribute this high performance to the optimal combination of
CNT (carbon nanotube; double-layer capacitance) and Zn2SnO4/SnO2 …
In this study, we demonstrate rapid and facile supersonic cold spray deposition of Zn2SnO4/SnO2/CNT nanocomposite supercapacitor electrodes with promising combinations of power and energy density. Cyclic voltammetry confirmed the capacitive behavior of the optimized electrode, with specific capacitance reaching 260 F·g–1 at a current density of 10 A·g–1. We attribute this high performance to the optimal combination of CNT (carbon nanotube; double-layer capacitance) and Zn2SnO4/SnO2 (pseudocapacitance) properties. The mesoporous and accessible surface of the CNT significantly contributed to the excellent retention (approximately 93%) of the specific capacitance after 15000 galvanostatic charge/discharge cycles. In addition, the supercapacitor exhibited a remarkable energy density, electrochemical properties, and mechanical stability. The materials and approach presented here can enable cost-effective, efficient, and scalable production of high-performance supercapacitor electrodes.
ACS Publications
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