Surface layering at the mercury-electrolyte interface
X-ray reflectometry reveals atomic layering at a liquid-liquid interface—mercury in a 0.01 M
NaF<? format?> solution. The interface width exceeds capillary wave theory predictions and
displays an anomalous dependence on the voltage applied across it, displaying a minimum
positive of the potential of zero charge. The latter is explained by electrocapillary effects and
an additional intrinsic broadening of the interface profile, tentatively assigned to polarization
of the conduction electrons due to the electric field of the electrochemical double layer at the …
NaF<? format?> solution. The interface width exceeds capillary wave theory predictions and
displays an anomalous dependence on the voltage applied across it, displaying a minimum
positive of the potential of zero charge. The latter is explained by electrocapillary effects and
an additional intrinsic broadening of the interface profile, tentatively assigned to polarization
of the conduction electrons due to the electric field of the electrochemical double layer at the …
Surface Layering at the Mercury-Electrolyte Interface
BM Ocko, A Elsen, BM Murphy, L Tamam… - Physical Review …, 2010 - osti.gov
X-ray reflectometry reveals atomic layering at a liquid-liquid interface--mercury in a 0.01 M
NaF solution. The interface width exceeds capillary wave theory predictions and displays an
anomalous dependence on the voltage applied across it, displaying a minimum positive of
the potential of zero charge. The latter is explained by electrocapillary effects and an
additional intrinsic broadening of the interface profile, tentatively assigned to polarization of
the conduction electrons due to the electric field of the electrochemical double layer at the …
NaF solution. The interface width exceeds capillary wave theory predictions and displays an
anomalous dependence on the voltage applied across it, displaying a minimum positive of
the potential of zero charge. The latter is explained by electrocapillary effects and an
additional intrinsic broadening of the interface profile, tentatively assigned to polarization of
the conduction electrons due to the electric field of the electrochemical double layer at the …