Synthesis, structure, and hydroboration reactivity of anionic nickel (0) complexes supported by bidentate NHC-pyridone ligands
M Afandiyeva, AA Kadam, X Wu, WW Brennessel… - …, 2022 - ACS Publications
A family of anionic, formally nickel (0) complexes supported by bidentate NHC–pyridone
ligands is described. The unsymmetric chelating environment and capping [K (18-crown-6)]+
countercation allow isolation of single-component, monometallic complexes in high yield.
The steric and electronic properties are assessed through a battery of experimental (NMR,
IR, UV–vis, X-ray diffraction) and computational tools. Catalytic activity for highly branched-
selective hydroboration of styrene with HBpin is demonstrated. Control experiments …
ligands is described. The unsymmetric chelating environment and capping [K (18-crown-6)]+
countercation allow isolation of single-component, monometallic complexes in high yield.
The steric and electronic properties are assessed through a battery of experimental (NMR,
IR, UV–vis, X-ray diffraction) and computational tools. Catalytic activity for highly branched-
selective hydroboration of styrene with HBpin is demonstrated. Control experiments …
Synthesis, Structure, and Hydroboration Reactivity of Anionic Nickel (0) Complexes Supported by Bidentate NHC-Pyridone Ligands
CR Kennedy, M Afandiyeva, X Wu, A Kadam… - 2022 - chemrxiv.org
A family of anionic, formally nickel (0) complexes supported by bidentate NHC–pyridone
ligands is described. The unsymmetric chelating environment and capping [K (18-crown-6)]+
countercation allow isolation of single-component, monometallic complexes in high yield.
The steric and electronic properties are assessed through a battery of experimental (NMR,
IR, UV/vis, X-ray diffraction) and computational tools. Catalytic activity for highly branched-
selective hydroboration of styrene with HBpin is demonstrated. Control experiments …
ligands is described. The unsymmetric chelating environment and capping [K (18-crown-6)]+
countercation allow isolation of single-component, monometallic complexes in high yield.
The steric and electronic properties are assessed through a battery of experimental (NMR,
IR, UV/vis, X-ray diffraction) and computational tools. Catalytic activity for highly branched-
selective hydroboration of styrene with HBpin is demonstrated. Control experiments …
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