Synthesis and Self-Assembly of CO2–Temperature Dual Stimuli-Responsive Triblock Copolymers
Poly (N, N-dimethylaminoethyl methacrylate)(PDMAEMA) with a β-cyclodextrin (β-CD) at the
chain end was synthesized via atom transfer radical polymerization (ATRP); poly (ε-
caprolactone)(PCL) with a− C C–segment and an adamantane (Ada) group at two ends,
respectively, was prepared through ring-opening polymerization (ROP), and poly (N-
isopropylacrylamide)(PNIPAM) with a− S–C (S)–S–segment, which can be converted into a
thiol group, was yielded by reversible addition–fragmentation chain transfer polymerization …
chain end was synthesized via atom transfer radical polymerization (ATRP); poly (ε-
caprolactone)(PCL) with a− C C–segment and an adamantane (Ada) group at two ends,
respectively, was prepared through ring-opening polymerization (ROP), and poly (N-
isopropylacrylamide)(PNIPAM) with a− S–C (S)–S–segment, which can be converted into a
thiol group, was yielded by reversible addition–fragmentation chain transfer polymerization …
[引用][C] Synthesis and Self-Assembly of CO2–Temperature Dual Stimuli-Responsive Triblock Copolymers
L Bo-wen, Z Hang, Z Si-tong, Z Hui-juan, F An-Chao… - 2014