Synthesis of an F-BODIPY [2] catenane using the chemistry of bis (dipyrrinato) metal complexes
Chemical Communications, 2017•pubs.rsc.org
ML2 type complexes of an olefin terminated 5H-dipyrrin ligand can be subjected to twofold
ring closing metathesis to give bis (dipyrrinato) copper (II) and bis (dipyrrinato) zinc (II)[2]
catenates. Demetalation of the copper (II)[2] catenate with KCN/N2H4· H2O gave the
corresponding bis (dipyrrin)[2] catenand. The boron difluoride complex of this bis (dipyrrin)
was obtained as the first fluorescent F-BODIPY [2] catenane.
ring closing metathesis to give bis (dipyrrinato) copper (II) and bis (dipyrrinato) zinc (II)[2]
catenates. Demetalation of the copper (II)[2] catenate with KCN/N2H4· H2O gave the
corresponding bis (dipyrrin)[2] catenand. The boron difluoride complex of this bis (dipyrrin)
was obtained as the first fluorescent F-BODIPY [2] catenane.
ML2 type complexes of an olefin terminated 5H-dipyrrin ligand can be subjected to twofold ring closing metathesis to give bis(dipyrrinato)copper(II) and bis(dipyrrinato)zinc(II) [2]catenates. Demetalation of the copper(II) [2]catenate with KCN/N2H4·H2O gave the corresponding bis(dipyrrin) [2]catenand. The boron difluoride complex of this bis(dipyrrin) was obtained as the first fluorescent F-BODIPY [2]catenane.
The Royal Society of Chemistry以上显示的是最相近的搜索结果。 查看全部搜索结果