[PDF][PDF] Synthesis of some novel hydrazide-hydrazones derived from etodolac as potential anti-prostate cancer agents

HC Koc, I Atlihan, P Mega-Tiber, OYA Orun… - J. Res …, 2022 - jrespharm.com
J. Res. Pharm, 2022jrespharm.com
(R, S)-Etodolac [1, 8-diethyl-1, 3, 4, 9-tetrahydrapyrano (3, 4-b) indole-1-acetic acid] is a
nonsteroidal antiinflammatory drug that contains carboxylic acid group with the structure of
pyrano [3, 4-b] indole. In this study, a series of novel (R, S)-Etodolac derivatives (3a-l)
bearing hydrazide-hydrazone moiety were synthesized. The structures of these compounds
were characterized by spectral (1H-NMR and FT-IR analyses) methods. All synthesized
compounds were screened for anticancer activity against androgen-independent prostate …
Abstract
(R, S)-Etodolac [1, 8-diethyl-1, 3, 4, 9-tetrahydrapyrano (3, 4-b) indole-1-acetic acid] is a nonsteroidal antiinflammatory drug that contains carboxylic acid group with the structure of pyrano [3, 4-b] indole. In this study, a series of novel (R, S)-Etodolac derivatives (3a-l) bearing hydrazide-hydrazone moiety were synthesized. The structures of these compounds were characterized by spectral (1H-NMR and FT-IR analyses) methods. All synthesized compounds were screened for anticancer activity against androgen-independent prostate adenocarcinoma (PC-3, DU-145) and androgen-dependent prostate adenocarcinoma (LNCaP) cell lines by using WST-8 colorimetric method. This method was used for cell viability and cytotoxicity analysis. Compound 3b (SGK-720)[2-(1, 8-diethyl-1, 3, 4, 9-tetrahydropyrano [3, 4-b] indole-1-yl) acetic acid [(2, 6-dichlorophenyl) methylene] hydrazides] showed 10.36, 5.24, 15.53 µM anticancer activity against PC3, DU145, LNCaP cancer cell lines, respectively. According to JC-1 mitochondrial membrane potential test and Annexin V/PI staining, 3b was found to have apoptotic effect on these cancer cells. It is concluded that compound 3b containing 2, 6-dichloro substituents may be one of the candidate molecules to cope with prostate cancer.
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