Tandem colloidal quantum dot solar cells employing a graded recombination layer

X Wang, GI Koleilat, J Tang, H Liu, IJ Kramer… - Nature …, 2011 - nature.com
X Wang, GI Koleilat, J Tang, H Liu, IJ Kramer, R Debnath, L Brzozowski, DAR Barkhouse…
Nature photonics, 2011nature.com
Tuning of the electronic bandgap in colloidal quantum dots (CQDs) by changing their size
enables the spectral response of CQD-based photodetectors,,,, and photovoltaic,,,,,, devices
to be tailored. Multi-junction solar cells made from a combination of CQDs of differing sizes
and thus bandgaps are a promising means by which to increase the energy harvested from
the Sun's broad spectrum. Here, we report the first CQD tandem solar cells using the size-
effect tuning of a single CQD material, PbS. We use a graded recombination layer to provide …
Abstract
Tuning of the electronic bandgap in colloidal quantum dots (CQDs) by changing their size enables the spectral response of CQD-based photodetectors,,,, and photovoltaic,,,,,, devices to be tailored. Multi-junction solar cells made from a combination of CQDs of differing sizes and thus bandgaps are a promising means by which to increase the energy harvested from the Sun's broad spectrum. Here, we report the first CQD tandem solar cells using the size-effect tuning of a single CQD material, PbS. We use a graded recombination layer to provide a progression of work functions from the hole-accepting electrode in the bottom cell to the electron-accepting electrode in the top cell, allowing matched electron and hole currents to meet and recombine. Our tandem solar cell has an open-circuit voltage of 1.06 V, equal to the sum of the two constituent single-junction devices, and a solar power conversion efficiency of up to 4.2%.
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