Tetraalkylphosphonium polyoxometalates: Electroactive,“task-specific” ionic liquids
PG Rickert, MR Antonio, MA Firestone… - Dalton …, 2007 - pubs.rsc.org
Dalton Transactions, 2007•pubs.rsc.org
… In this report, we demonstrate that the pairing of selected polyoxometalate anions with
appropriate tetraalkylphosphonium (R 3 R′P + ) cations yields examples of an original
family of ILs, among them an ambient-temperature “liquid POM” 12 with significantly
improved thermal stability, and summarize our initial efforts to characterize this novel liquid
salt. … Moreover, through the use of ionic liquids, other characteristics of POMs (eg,
nanomolecular morphology, electronic and photochemical properties) might be more …
appropriate tetraalkylphosphonium (R 3 R′P + ) cations yields examples of an original
family of ILs, among them an ambient-temperature “liquid POM” 12 with significantly
improved thermal stability, and summarize our initial efforts to characterize this novel liquid
salt. … Moreover, through the use of ionic liquids, other characteristics of POMs (eg,
nanomolecular morphology, electronic and photochemical properties) might be more …
The pairing of selected polyoxometalate (POM) anions with appropriate tetraalkylphosphonium cations is shown to yield an original family of ionic liquids, among them an ambient-temperature “liquid POM”.
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