Texture regulation of metal–organic frameworks, microwave absorption mechanism‐oriented structural optimization and design perspectives

Z Gao, A Iqbal, T Hassan, L Zhang, H Wu… - Advanced …, 2022 - Wiley Online Library
Advanced Science, 2022Wiley Online Library
Texture regulation of metal–organic frameworks (MOFs) is essential for controlling their
electromagnetic wave (EMW) absorption properties. This review systematically summarizes
the recent advancements in texture regulation strategies for MOFs, including etching and
exchange of central ions, etching and exchange of ligands, chemically induced self‐
assembly, and MOF‐on‐MOF heterostructure design. Additionally, the EMW absorption
mechanisms in approaches based on structure–function dependencies, including nano …
Abstract
Texture regulation of metal–organic frameworks (MOFs) is essential for controlling their electromagnetic wave (EMW) absorption properties. This review systematically summarizes the recent advancements in texture regulation strategies for MOFs, including etching and exchange of central ions, etching and exchange of ligands, chemically induced self‐assembly, and MOF‐on‐MOF heterostructure design. Additionally, the EMW absorption mechanisms in approaches based on structure–function dependencies, including nano‐micro topological engineering, defect engineering, interface engineering, and hybrid engineering, are comprehensively explored. Finally, current challenges and future research orientation are proposed. This review aims to provide new perspectives for designing MOF‐derived EMW‐absorption materials to achieve essential breakthroughs in mechanistic investigations in this promising field.
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