The Mechanism of Stereospecific CH Oxidation by Fe(Pytacn) Complexes: Bioinspired Non‐Heme Iron Catalysts Containing cis‐Labile Exchangeable Sites
A detailed mechanistic study of the hydroxylation of alkane C H bonds using H2O2 by a
family of mononuclear non heme iron catalysts with the formula [FeII (CF3SO3) 2 (L)] is
described, in which L is a tetradentate ligand containing a triazacyclononane tripod and a
pyridine ring bearing different substituents at the α and γ positions, which tune the electronic
or steric properties of the corresponding iron complexes. Two inequivalent cis‐labile
exchangeable sites, occupied by triflate ions, complete the octahedral iron coordination …
family of mononuclear non heme iron catalysts with the formula [FeII (CF3SO3) 2 (L)] is
described, in which L is a tetradentate ligand containing a triazacyclononane tripod and a
pyridine ring bearing different substituents at the α and γ positions, which tune the electronic
or steric properties of the corresponding iron complexes. Two inequivalent cis‐labile
exchangeable sites, occupied by triflate ions, complete the octahedral iron coordination …
The Mechanism of Stereospecific CH Oxidation by Fe (Pytacn) Complexes: Bioinspired Non-Heme Iron Catalysts Containing cis-Labile Exchangeable Sites
I Prat Casellas, V Postils Ribó… - … : a European Journal …, 2013 - dugi-doc.udg.edu
A detailed mechanistic study of the hydroxylation of alkane CH bonds using H2O2 by a
family of mononuclear non heme iron catalysts with the formula [FeII (CF3SO3) 2 (L)] is
described, in which L is a tetradentate ligand containing a triazacyclononane tripod and a
pyridine ring bearing different substituents at the and positions, which tune the electronic or
steric properties of the corresponding iron complexes. Two inequivalent cis-labile
exchangeable sites, occupied by triflate ions, complete the octahedral iron coordination …
family of mononuclear non heme iron catalysts with the formula [FeII (CF3SO3) 2 (L)] is
described, in which L is a tetradentate ligand containing a triazacyclononane tripod and a
pyridine ring bearing different substituents at the and positions, which tune the electronic or
steric properties of the corresponding iron complexes. Two inequivalent cis-labile
exchangeable sites, occupied by triflate ions, complete the octahedral iron coordination …
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