shown that for small deformation the molecular mechanism of stretching is dominated by the
slippage of chains. Hardening of the rubber at a high deformation is due to inextensibility as
described by the tube concept. This free energy of deformation agrees well with experiment.
The resulting free energy is F k BT= 1 2 N c∑ i= 1 3 (1− α 2) λ i 2 1− α 2 Z ̄ λ i 2− log 1− α
2∑ i= 3 3 λ i 2+ 1 2 ns∑ i= 1 3 λ i 2 (1+ η)(1− α 2)(1+ ηλ i 2)(1− α 2 σλ i 2)+ log (1+ ηλ i 2) …