Thermodynamics of mixtures containing amines. XI. Liquid+ liquid equilibria and molar excess enthalpies at 298.15 K for N-methylaniline+ hydrocarbon systems …
Liquid+ liquid equilibrium (LLE) temperatures have been determined for the N-
methylaniline+ tetradecane, or+ hexadecane systems by the method of the critical
opalescence using a laser scattering technique. The coexistence curves have an upper
critical solution temperature (UCST) and, due to size effects, are skewed towards high mole
fractions of the amine. Excess molar enthalpies, HmE, at 298.15 K and atmospheric
pressure, have been also measured over the entire mole fraction range, using a Tian–Calvet …
methylaniline+ tetradecane, or+ hexadecane systems by the method of the critical
opalescence using a laser scattering technique. The coexistence curves have an upper
critical solution temperature (UCST) and, due to size effects, are skewed towards high mole
fractions of the amine. Excess molar enthalpies, HmE, at 298.15 K and atmospheric
pressure, have been also measured over the entire mole fraction range, using a Tian–Calvet …
Thermodynamics of mixtures containing amines. XI. Liquid plus liquid equilibria and molar excess enthalpies at 298.15 K for N-methylaniline plus hydrocarbon …
J Antonio Gonzalez, I Alonso… - Journal of Chemical …, 2013 - hero.epa.gov
Liquid+ liquid equilibrium (LLE) temperatures have been determined for the N-
methylaniline+ tetradecane, or+ hexadecane systems by the method of the critical
opalescence using a laser scattering technique. The coexistence curves have an upper
critical solution temperature (UCST) and, due to size effects, are skewed towards high mole
fractions of the amine. Excess molar enthalpies, Hm (E), at 298.15 K and atmospheric
pressure, have been also measured over the entire mole fraction range, using a Tian-Calvet …
methylaniline+ tetradecane, or+ hexadecane systems by the method of the critical
opalescence using a laser scattering technique. The coexistence curves have an upper
critical solution temperature (UCST) and, due to size effects, are skewed towards high mole
fractions of the amine. Excess molar enthalpies, Hm (E), at 298.15 K and atmospheric
pressure, have been also measured over the entire mole fraction range, using a Tian-Calvet …
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