Towards uranium catalysts

AR Fox, SC Bart, K Meyer, CC Cummins - Nature, 2008 - nature.com
catalytic future of uranium, in which the applications of the element extend far beyond the
nuclear industry. Most excitingly, the ability of uranium … conventional, transition-metal catalysts. …

From chemical curiosities and trophy molecules to uranium-based catalysis: developments for uranium catalysis as a new facet in molecular uranium chemistry

DR Hartline, K Meyer - Jacs Au, 2021 - ACS Publications
… Looking toward the future, we will discuss related synthetic cycles on the cusp of becoming
… examine molecular uranium catalysts which utilize these two strategies to enable catalytic

The role of uranium–arene bonding in H2O reduction catalysis

DP Halter, FW Heinemann, L Maron, K Meyer - Nature Chemistry, 2018 - nature.com
… The reactivity of uranium compounds towards small … of uranium–arene δ bonding in
intermediates of the catalytic cycle, … 2 O to the trivalent uranium catalyst. Both aspects were …

Chemistry of actinide centers in heterogeneous catalytic transformations of small molecules

J Leduc, M Frank, L Jürgensen, D Graf, A Raauf… - … Catalysis, 2019 - ACS Publications
… and unexplored potential toward alternative catalytic energy production processes. … (3,4)
Since the first report in 1974 on the extraordinary catalytic activity of an organometallic uranium

… of tributyl phosphate grafted carbon nanotubes by the floating catalytic chemical vapor deposition method and their sorption behavior towards uranium

S Mishra, J Dwivedi, A Kumar… - New Journal of …, 2016 - pubs.rsc.org
… Carbon nanotubes were prepared by the floating catalyst horizontal … Ferrocene acted both
as a floating catalyst and as a … group of the TBP ligand towards the interaction of uranium. …

Highly efficient electrocatalytic uranium extraction from seawater over an amidoxime‐functionalized In–N–C catalyst

X Liu, Y Xie, M Hao, Z Chen, H Yang… - Advanced …, 2022 - Wiley Online Library
uranium uptake capacity. Meanwhile, better understanding of the catalytic mechanism for
uranium … We thus studied the selectivity of In−N x −C−R towards uranium over other metal ions …

Molecular Models of Atomically Dispersed Uranium at MoS2 Surfaces Reveal Cooperative Mechanism of Water Reduction

K Patra, WW Brennessel… - Journal of the American …, 2024 - ACS Publications
uranium at molybdenum sulfide surfaces toward water, modeling key … associated with the
HER of U@MoS 2 catalysts. … in catalytic water reduction by uranium single-atom catalysts on …

Depleted uranium catalysts for chlorine production

AP Amrute, F Krumeich, C Mondelli… - Chemical Science, 2013 - pubs.rsc.org
This study demonstrates depleted uranium as a remarkable heterogeneous catalyst for the
oxidation of HCl to Cl2. This reaction comprises a sustainable approach to valorise byproduct …

Advanced photocatalysts for uranium extraction: elaborate design and future perspectives

T Chen, K Yu, C Dong, X Yuan, X Gong, J Lian… - Coordination Chemistry …, 2022 - Elsevier
catalyst, in which holes have oxidation and electrons have reducibility. During the
photoreduction of uranium in … advanced photocatalysts towards photocatalytic uranium reduction. …

Heterometallic clusters with uranium–metal bonds supported by double-layer nitrogen–phosphorus ligands

Q Zhu, W Fang, L Maron, C Zhu - Accounts of Chemical Research, 2022 - ACS Publications
… and catalysis. However, reports of the isolation of heterometallic clusters with uranium–…
The U≡TM triple bonds are strongly polarized toward TMs, eg, 80–86% for Fe and 72–82% …