Translational spectroscopy of H(D) atom fragments arising from the photodissociation of H>2>S(D>2>S):
A redetermination of D>o>>o>(SH) — University of Bristol … Translational spectroscopy of H(D)
atom fragments arising from the photodissociation of H 2 S(D 2 S): A redetermination of D o
o (SH) … Translational spectroscopy of H(D) atom fragments arising from the
photodissociation of H 2 S(D 2 S): A redetermination of D o o (SH) …

The technique of H/D atom photofragment translational spectroscopy has been used to
further investigate the collision-free photodissociation of H2S and D2S molecules both in the
near ultraviolet (at 218.2 and 221.6 nm) and in the vacuum ultraviolet (at 121.6 nm).
Measurements of the H/D atom photofragment angular distributions confirms that the near
UV dissociation occurs promptly, following a perpendicular photo-excitation. More than 99%
of the resulting SH/SD fragments are formed in their ground vibronic level, with a ca. 3: 2 …