Triple-junction perovskite–perovskite–silicon solar cells with power conversion efficiency of 24.4%

H Hu, SX An, Y Li, S Orooji, R Singh… - Energy & …, 2024 - pubs.rsc.org
Energy & Environmental Science, 2024pubs.rsc.org
The recent tremendous progress in monolithic perovskite-based double-junction solar cells
is just the start of a new era of ultra-high-efficiency multi-junction photovoltaics. We report on
triple-junction perovskite–perovskite–silicon solar cells with a record power conversion
efficiency of 24.4%. Optimizing the light management of each perovskite sub-cell (∼ 1.84
and∼ 1.52 eV for top and middle cells, respectively), we maximize the current generation up
to 11.6 mA cm− 2. Key to this achievement was our development of a high-performance …
The recent tremendous progress in monolithic perovskite-based double-junction solar cells is just the start of a new era of ultra-high-efficiency multi-junction photovoltaics. We report on triple-junction perovskite–perovskite–silicon solar cells with a record power conversion efficiency of 24.4%. Optimizing the light management of each perovskite sub-cell (∼1.84 and ∼1.52 eV for top and middle cells, respectively), we maximize the current generation up to 11.6 mA cm−2. Key to this achievement was our development of a high-performance middle perovskite sub-cell, employing a stable pure-α-phase high-quality formamidinium lead iodide perovskite thin film (free of wrinkles, cracks, and pinholes). This enables a high open-circuit voltage of 2.84 V in a triple junction. Non-encapsulated triple-junction devices retain up to 96.6% of their initial efficiency if stored in the dark at 85 °C for 1081 h.
The Royal Society of Chemistry
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