Ultrastable halide perovskite CsPbBr3 photoanodes achieved with electrocatalytic glassy-carbon and boron-doped diamond sheets

Z Zhu, M Daboczi, M Chen, Y Xuan, X Liu… - Nature …, 2024 - nature.com
Nature Communications, 2024nature.com
Halide perovskites exhibit exceptional optoelectronic properties for photoelectrochemical
production of solar fuels and chemicals but their instability in aqueous electrolytes hampers
their application. Here we present ultrastable perovskite CsPbBr3-based photoanodes
achieved with both multifunctional glassy carbon and boron-doped diamond sheets coated
with Ni nanopyramids and NiFeOOH. These perovskite photoanodes achieve record
operational stability in aqueous electrolytes, preserving 95% of their initial photocurrent …
Abstract
Halide perovskites exhibit exceptional optoelectronic properties for photoelectrochemical production of solar fuels and chemicals but their instability in aqueous electrolytes hampers their application. Here we present ultrastable perovskite CsPbBr3-based photoanodes achieved with both multifunctional glassy carbon and boron-doped diamond sheets coated with Ni nanopyramids and NiFeOOH. These perovskite photoanodes achieve record operational stability in aqueous electrolytes, preserving 95% of their initial photocurrent density for 168 h of continuous operation with the glassy carbon sheets and 97% for 210 h with the boron-doped diamond sheets, due to the excellent mechanical and chemical stability of glassy carbon, boron-doped diamond, and nickel metal. Moreover, these photoanodes reach a low water-oxidation onset potential close to +0.4 VRHE and photocurrent densities close to 8 mA cm−2 at 1.23 VRHE, owing to the high conductivity of glassy carbon and boron-doped diamond and the catalytic activity of NiFeOOH. The applied catalytic, protective sheets employ only earth-abundant elements and straightforward fabrication methods, engineering a solution for the success of halide perovskites in stable photoelectrochemical cells.
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