Using metal-organic templates to steer the growth of Fe and Co nanoclusters

R Decker, U Schlickum, F Klappenberger… - Applied Physics …, 2008 - pubs.aip.org
Regularly sized Fe and Co nanostructures are created using two-dimensional metal-organic
honeycomb lattices as templates. They consist of dicarbonitrile-polyphenyl molecules
coordinated to Co centers on Ag (111). Subsequently deposited Fe or Co atoms nucleate
clusters at specific sites on top of the metal-organic lattices while leaving their hexagonal
pores empty. Choosing the deposition temperature, one can selectively decorate the
molecules (120 K) or the Co coordination nodes (190 K) with Fe. The distance between the …
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