Wall slip of molten high density polyethylenes. II. Capillary rheometer studies

SG Hatzikiriakos, JM Dealy - Journal of rheology, 1992 - pubs.aip.org
Above the critical stress for slip, the procedures normally used to analyze the results of
capillary flow data give anomalous results. In particular, the Bagley plots are curved, even
when a variation of viscosity with pressure is not anticipated, and the Mooney technique
used to calculate the slip velocity gives results that indicate that the slip velocity depends on
the L/D ratio. It is proposed that these phenomena arise from the dependence of the slip
velocity on the wall normal stress, which implies a dependence on pressure. Based on this …
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