Well-defined polymethylene-based block co/terpolymers by combining anthracene/maleimide diels–alder reaction with polyhomologation

N Alkayal, N Hadjichristidis - Polymer Chemistry, 2015 - pubs.rsc.org
A novel strategy towards well-defined polymethylene-based co/terpolymers, by combining
the anthracene/maleimide Diels–Alder reaction with polyhomologation, is presented. For the
synthesis of diblock copolymers the following approach was applied:(a) synthesis of α-
anthracene-ω-hydroxy-polymethylene by polyhomologation using tri (9-anthracene-methyl
propyl ether) borane as the initiator,(b) synthesis of furan-protected-maleimide-terminated
poly (ε-caprolactone) or polyethylene glycol and (c) the Diels–Alder reaction between the …

[PDF][PDF] Well-defined Polymethylene-Based Co/Terpolymers by Combining Anthracene/Maleimide Diels-Alder Reaction with Polyhomologation

N Hadjichristidis, N Alkayal - 2015 - repository.kaust.edu.sa
A novel strategy towards well-defined polymethylene-based co/terpolymers, by combining
anthracene/maleimide Diels-Alder reaction with polyhomologation, is presented. For the
synthesis of diblock copolymers the following approach was applied: a) synthesis of α-
anthracene-ω-hydroxy-polymethylene by polyhomologation using tri (9-anthracene-methyl
propyl ether) borane as initiator, b) synthesis of furan-protected-maleimide-terminated poly
(ε-caprolactone) or polyethylene glycol and c). Diels-Alder reaction between the anthracene …
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