Design of Lewis-acid centres in zeolitic matrices for the conversion of renewables

PY Dapsens, C Mondelli… - Chemical Society Reviews, 2015 - pubs.rsc.org
paired lattice sites, which are stable even at distances below 5 Å. … hydride shift, and the
nature of the active site in Sn-BEA, an open … In this work, the authors suggest that the active sites

Analysis and control of acid sites in zeolites

A Palčić, V Valtchev - Applied Catalysis A: General, 2020 - Elsevier
… of active sites in zeolite frameworks. It is focused on the … of zeolite Brønsted sites may occur,
and Lewis acid sites with Si … The two most frequent types of Al arrangements are paired (…

Lewis acid zeolites for biomass conversion: Perspectives and challenges on reactivity, synthesis, and stability

HY Luo, JD Lewis… - Annual review of chemical …, 2016 - annualreviews.org
… the Lewis acidity of active sites in Lewis acid zeolites is essential for designing materials to
catalyze … Pyridine adsorption coupled with FTIR spectroscopy has been traditionally used to …

The nature and catalytic function of cation sites in zeolites: a computational perspective

G Li, EA Pidko - ChemCatChem, 2019 - Wiley Online Library
… The reactivity of zeolite catalysts can be tailored by … of versatile Brønsted acid, Lewis acid
and redox-active catalytic sites. … possibility of forming paired Lewis acid sites capable of concert …

Acidic properties and structure–activity correlations of solid acid catalysts revealed by solid-state nmr spectroscopy

A Zheng, S Li, SB Liu, F Deng - Accounts of chemical research, 2016 - ACS Publications
… , and ion-paired with superacidic sites. For the latter, the … and Lewis acid centers play a crucial
role during catalytic reactions… /Lewis acid synergy observed in dealuminated H–Y zeolites

Water structures on acidic zeolites and their roles in catalysis

Q Liu, JA van Bokhoven - Chemical Society Reviews, 2024 - pubs.rsc.org
… water molecules and active sites on catalysts exhibit distinct … Brønsted and Lewis acidic
zeolites will be the focus of this … Ion-paired hydronium ions with higher protonation degree and …

Metal sites in zeolites: synthesis, characterization, and catalysis

Q Zhang, S Gao, J Yu - Chemical reviews, 2022 - ACS Publications
… well-defined metal active sites within zeolites and advanced characterization … Lewis acid
sites can accept electron pairs from substrates without generating a charge imbalance in zeolite

Engineering Lewis Acidity in Zeolite Catalysts by Electrochemical Release of Heteroatoms during Synthesis

G Ivanushkin, M Dusselier - Chemistry of Materials, 2023 - ACS Publications
active heteroatom precursors allows one to synthesize zeolite catalysts with unprecedented
Lewis acid site (… , and in catalytic tests, this leads to materials so rich in active sites that they …

The nature of active sites in zeolites: influence on catalyst performance

A Humphries, DH Harris, P O'connor - … in surface science and catalysis, 1993 - Elsevier
zeolite, and requires pairscontaining no Lewis acid sites [154]. In general Kazansky and
co-workers feel the many different types of Lewis acid sites, both within and outside the zeolitic

Opportunities in catalysis over metal-zeotypes enabled by descriptions of active centers beyond their binding site

JW Harris, JS Bates, BC Bukowski, J Greeley… - … Catalysis, 2020 - ACS Publications
… because they can confine Lewis acidic sites within hydrophobic voids to … sites in Sn-zeotypes
has been proposed, including (i) paired Sn sites in six-membered rings of Beta zeolites