Generation and reactivity of putative support systems, Ce-Al neutral binary oxide nanoclusters: CO oxidation and C–H bond activation

ZC Wang, S Yin, ER Bernstein - The Journal of Chemical Physics, 2013 - pubs.aip.org
Both ceria (CeO 2) and alumina (Al 2 O 3) are very important catalyst support materials.
Neutral binary oxide nanoclusters (NBONCs), Ce x Al y O z, are generated and detected in …

Theoretical perspective on CO oxidation over small cobalt oxide clusters

R Molavi, R Safaiee, MH Sheikhi, N Hassani - Chemical Physics Letters, 2021 - Elsevier
In this work, CO oxidation on oxidized cobalt oxide clusters, ie, C o O nO 2 (n= 2, 3, 4) and
(Co 3 O 4) nO 2 (n= 1, 2) are studied using density functional theory calculations. CO …

Al12X (X = Ni, Pd, Pt, Ti, and Zr) Clusters: Promising Low-Cost and High-Activity Catalysts for CO Oxidation

L Guo, X Zhang - The Journal of Physical Chemistry C, 2014 - ACS Publications
CO oxidation on the surface of various Al12X (X= Ni, Pd, Pt, Ti, and Zr) clusters is
investigated by density functional theory (DFT) calculations. The molecular structures and …

Experimental and Theoretical Study of the Reactions between Cerium Oxide Cluster Anions and Carbon Monoxide: Size-Dependent Reactivity of CenO2n+1 (n …

XN Wu, XL Ding, SM Bai, B Xu, SG He… - The Journal of Physical …, 2011 - ACS Publications
Reactions of cerium oxide cluster anions with carbon monoxide are investigated by time-of-
flight mass spectrometry and density functional theory computations aided with molecular …

Origin of Support Effects on the Reactivity of a Ceria Cluster

L Cheng, D Mei, Q Ge - The Journal of Physical Chemistry C, 2009 - ACS Publications
The interaction between an active oxide and an oxide support plays a critical role in
controlling the reactivity of oxide-on-oxide catalysts. In the present study, the reactivity of a …

Role of H2O Adsorption in CO Oxidation over Cerium-Oxide Cluster Anions (CeO2)nO (n = 1–4)

JJ Chen, SD Wang, XL Ding, SG He - The Journal of Physical …, 2024 - ACS Publications
Water (H2O) is ubiquitous in the environment and inevitably participates in many surface
reactions, including CO oxidation. Acquiring a fundamental understanding of the roles of …

Gas-phase neutral binary oxide clusters: distribution, structure, and reactivity toward CO

ZC Wang, S Yin, ER Bernstein - The Journal of Physical Chemistry …, 2012 - ACS Publications
Neutral binary (vanadium–cobalt) oxide clusters are generated and detected in the gas
phase for the first time. Their reactivities toward carbon monoxide (CO) are studied both …

Reactivity trends in the oxidation of CO by anionic transition metal oxide clusters

JU Reveles, GE Johnson, SN Khanna… - The Journal of …, 2010 - ACS Publications
Evidence obtained by experiments in the gas phase and density functional theory
calculations indicates that differences in the CO binding energy to the transition metal site …

Influence of stoichiometry and charge state on the structure and reactivity of cobalt oxide clusters with CO

GE Johnson, JU Reveles, NM Reilly… - The Journal of …, 2008 - ACS Publications
Cationic and anionic cobalt oxide clusters, generated by laser vaporization, were studied
using guided-ion-beam mass spectrometry to obtain insight into their structure and reactivity …

Oxidation of CO and NO on composition-selected cerium oxide cluster cations

S Hirabayashi, M Ichihashi - The Journal of Physical Chemistry A, 2013 - ACS Publications
The collisional reactions of composition-selected cerium oxide cluster cations, Ce n O m+(n=
2–6; m≤ 2 n), with CO and NO have been investigated under single collision conditions …