Formation of secondary Fe-oxyhydroxide phases during the dissolution of chlorite–effects on uranium sorption

E Krawczyk-Bärsch, T Arnold, H Reuther, F Brandt… - Applied …, 2004 - Elsevier
The formation of Fe-oxyhydroxide colloids resulting from the simulated weathering of chlorite
(CCa-2) was studied in batch experiments. The detected colloids showed a particle diameter …

Chlorite alteration in aqueous solutions and uranium removal by altered chlorite

E Kim, H Ahn, HY Jo, JH Ryu, YK Koh - Journal of hazardous materials, 2017 - Elsevier
Chlorite alteration and the U removal capacity of altered chlorite were investigated. Batch
kinetic dissolution tests using clinochlore CCa-2 were conducted for 60 days in aqueous …

Uranium sorption on oxyhydroxide minerals by surface complexation and precipitation

J Wang, W Zhou, Y Shi, Y Li, D Xian, N Guo… - Chinese Chemical …, 2022 - Elsevier
During the chemical weathering of the uranium mill tailings, released uranium could be
immobilized by the newly formed secondary minerals such as oxyhydroxides. A deeper …

Heterogeneous formation of ferric oxide nanoparticles on chlorite surfaces studied by X-ray absorption spectromicroscopy (STXM)

F Brandt, T Schäfer, F Claret, D Bosbach - Chemical Geology, 2012 - Elsevier
The homogeneous and heterogeneous formation of ferric iron oxides from acidic solution
(pH 2.06–2.50) has been studied in the presence of chlorite under constant pH conditions …

Sulfidization of lepidocrocite and its effect on uranium phase distribution and reduction

VG Alexandratos, T Behrends… - … et Cosmochimica Acta, 2014 - Elsevier
Sulfidization of iron oxyhydroxides can be accompanied by a release of adsorbed uranium,
thus enhancing the mobility of uranium in systems undergoing a shift in redox conditions …

Carbonate effects on hexavalent uranium adsorption by iron oxyhydroxide

M Wazne, GP Korfiatis, X Meng - Environmental science & …, 2003 - ACS Publications
Carbonate dramatically affects the adsorption of uranium (U (VI)) onto iron hydroxides and
its mobility in the natural environment. Batch tests, zeta potential measurements, and Fourier …

Uranium retention on iron oxyhydroxides in post-mining environmental conditions

F Lahrouch, N Guo, MOJY Hunault, PL Solari… - Chemosphere, 2021 - Elsevier
Investigating uranium migration mechanisms related to the weathering of waste rocks is
essential for developing strategies that can address the potential environmental issues …

Uranium co-precipitation with iron oxide minerals

MC Duff, JU Coughlin, DB Hunter - Geochimica et Cosmochimica Acta, 2002 - Elsevier
In oxidizing environments, the toxic and radioactive element uranium (U) is most soluble and
mobile in the hexavalent oxidation state. Sorption of U (VI) on Fe-oxides minerals (such as …

Uranium incorporation into aluminum-substituted ferrihydrite during iron (II)-induced transformation

MS Massey, JS Lezama-Pacheco, FM Michel… - … Science: Processes & …, 2014 - pubs.rsc.org
Uranium retention processes (adsorption, precipitation, and incorporation into host minerals)
exert strong controls on U mobility in the environment, and understanding U retention is …

Sorption behavior of U (VI) on phyllite: experiments and modeling

T Arnold, T Zorn, H Zänker, G Bernhard… - Journal of contaminant …, 2001 - Elsevier
The sorption of U (VI) onto low-grade metamorphic rock phyllite was modeled with the
diffuse double layer model (DDLM) using the primary mineralogical constituents of phyllite …