Synthesis of Covalently Linked Oligo (phenyleneethynylene) Wires Incorporating Dithiafulvene Units: Redox‐Active “H‐Cruciforms”

FP Jørgensen, JF Petersen… - European Journal of …, 2017 - Wiley Online Library
Controlled alignment and self‐assembly of molecular wires is one of the challenges in the
field of molecular electronics. Here, we take an approach by which two oligo …

Synthesis of oligo (phenyleneethynylene) s with vertically disposed tetrathiafulvalene units

K Jennum, M Vestergaard, AH Pedersen, J Fock… - …, 2011 - thieme-connect.com
Functionalized oligo (phenyleneethynylene) s (OPEs) show potential as molecular wires for
molecular electronics. A selection of OPEs with vertically disposed extended …

Tetrathiafulvalene-based cruciform molecules

K Jennum, MB Nielsen - Chemistry Letters, 2011 - academic.oup.com
Molecules with two orthogonally oriented π-systems (cruciforms) have attracted interest by
virtue of the different conjugation pathways that exist between the individual parts of the …

Molecular scaffolding with tetrathiafulvalene—design and synthesis of new molecules for molecular electronics

MB Nielsen - Phosphorus, Sulfur, and Silicon and the Related …, 2011 - Taylor & Francis
Since the field of molecular electronics originated in the 1970s, the sulfur-containing
heterocycle tetrathiafulvalene (TTF) has played a leading role. The reason for this is its …

Synthesis of oligo (phenyleneethynylene)-tetrathiafulvalene cruciforms for molecular electronics

JK Sørensen, M Vestergaard, A Kadziola, K Kilså… - Organic …, 2006 - ACS Publications
Novel oligo (phenyleneethynylene)(OPE)-tetrathiafulvalene (TTF) cruciform molecules
containing thiol end-groups have been prepared and characterized. These redox-active …

A comprehensive study of extended tetrathiafulvalene cruciform molecules for molecular electronics: synthesis and electrical transport measurements

CR Parker, E Leary, R Frisenda, Z Wei… - Journal of the …, 2014 - ACS Publications
Cruciform-like molecules with two orthogonally placed π-conjugated systems have in recent
years attracted significant interest for their potential use as molecular wires in molecular …

Synthesis and characterization of cruciform-conjugated molecules based on tetrathiafulvalene

M Vestergaard, K Jennum, JK Sørensen… - The Journal of …, 2008 - ACS Publications
Stepwise acetylenic scaffolding provides cruciform-conjugated molecules with vertically
disposed π-systems, one being an extended tetrathiafulvene (TTF) unit. Two synthetic routes …

[PDF][PDF] A new class of extended tetrathiafulvalene cruciform molecules for molecular electronics with dithiafulvene-4, 5-dithiolate anchoring groups

CR Parker, Z Wei, CR Arroyo, K Jennum, T Li… - Adv Mater, 2013 - academia.edu
Development of functional organic molecules as components for molecular electronics has
attracted wide interest in recent years.[1] In particular, oligo (phenyleneethynylene) s (OPEs …

Convenient regioselective syntheses of isomeric bis (tetrathiafulvalenylethenyl) naphthalene π-donors

S González, N Martín, JL Segura, C Seoane - Tetrahedron letters, 1998 - Elsevier
Novel highly soluble isomeric tetrathiafulvalene (TTF) dimers with unusual
divinylnaphthalene spacers have been prepared from Wittig reactions. The cyclic …

Probing the conformational changes upon oxidation in cross-conjugated architectures featuring vinylogous TTF units

R Berridge, PJ Skabara, R Andreu, J Garín, J Orduna… - Tetrahedron letters, 2005 - Elsevier
We report the synthesis and electropolymerisation of 1, 3, 5-tris (1, 3-dithiole-2-
ylidenephenylene) benzene. The resulting polymer features extended tetrathiafulvalene …