Formation mechanism of anionic surfactant-templated mesoporous silica

C Gao, H Qiu, W Zeng, Y Sakamoto… - Chemistry of …, 2006 - ACS Publications
The synthesis mechanism of anionic surfactant-templated mesoporous silica (AMS) is
described. A family of highly ordered mesoporous silica structures have been synthesized …

Synthesis mechanism of cationic surfactant templating mesoporous silica under an acidic synthesis process

S Che, H Li, S Lim, Y Sakamoto, O Terasaki… - Chemistry of …, 2005 - ACS Publications
The presence of various counteranions in the interfacial region of the silicate− surfactant
mesophase introduces opportunities for manipulation of the phase structure. Well-ordered …

Molecular design of the surfactant and the co-structure-directing agent (CSDA) toward rational synthesis of targeted anionic surfactant templated mesoporous silica

C Gao, Y Sakamoto, O Terasaki… - Journal of Materials …, 2007 - pubs.rsc.org
The formation of anionic surfactant templated mesoporous silica (AMS) is investigated from
the perspective of the geometrical molecular design of the surfactant and the co-structure …

Amino and quaternary ammonium group functionalized mesoporous silica: An efficient ion-exchange method to remove anionic surfactant from AMS

H Zheng, C Gao, S Che - Microporous and mesoporous materials, 2008 - Elsevier
Amino and quaternary ammonium group functionalized mesoporous silicas have been
obtained by extracting the surfactant from anionic surfactant templated mesoporous silica …

A novel anionic surfactant templating route for synthesizing mesoporous silica with unique structure

S Che, AE Garcia-Bennett, T Yokoi, K Sakamoto… - Nature materials, 2003 - nature.com
Anionic surfactants are used in greater volume than any other surfactants because of their
highly potent detergency and low cost of manufacture. However, they have not been used as …

Ordered mesoporous silica derived from layered silicates

T Kimura, K Kuroda - Advanced Functional Materials, 2009 - Wiley Online Library
Here, the development of ordered mesoporous silica prepared by the reaction of layered
silicates with organoammonium surfactants is reviewed. The specific features of …

Direct synthesis of functional mesoporous silica by neutral pH nonionic surfactant assembly: factors affecting framework structure and composition

R Richer, L Mercier - Chemistry of Materials, 2001 - ACS Publications
The preparation of a wide range of organically functionalized wormhole-motif and
hexagonal mesoporous MSU-X silicas was achieved by a one-step synthesis process …

Synthesis of anionic-surfactant-templated mesoporous silica using organoalkoxysilane-containing amino groups

T Yokoi, H Yoshitake, T Tatsumi - Chemistry of materials, 2003 - ACS Publications
Mesoporous silica containing a large amount of aminopropyl groups has been successfully
synthesized via the anionic templating route. The electrostatic interaction between the …

Amino-functionalized mesoporous silica synthesized by an anionic surfactant templating route

T Yokoi, H Yoshitake, T Yamada, Y Kubota… - Journal of Materials …, 2006 - pubs.rsc.org
A “S− N+∼ I− pathway”(S−: anionic surfactant, N+: cationic amino group and I: inorganic
species) for the synthesis of mesoporous silica has been developed by using 3 …

Surfactant control of phases in the synthesis of mesoporous silica-based materials

Q Huo, DI Margolese, GD Stucky - Chemistry of Materials, 1996 - ACS Publications
The low-temperature formation of liquid-crystal-like arrays made up of molecular complexes
formed between molecular inorganic species and amphiphilic organic molecules is a …