Catalytic decarboxylative reactions are attractive as biomimetic reactions and
environmentally friendly reaction processes. In this review, the origin and recent …

The asymmetric decarboxylation of prochiral α-disubstituted malonic acids is an attractive
route to produce homochiral αsubstituted carboxylic acids. Various metal-catalysed and …

We describe a biomimetic organocatalytic enantioselective decarboxylative addition of
malonic acid half thioesters to imines. This simple protocol makes use of readily available …

The organocatalytic enantioselective decarboxylative Mannich reaction of malonic acid half
thioesters (MAHTs) with cyclic N‐sulfonyl ketimines by using N‐heteroarenesulfonyl …

An organocatalytic asymmetric decarboxylative amination reaction of β-keto acids is
described. Under mild reaction conditions, a series of chiral α-amino ketones were obtained …

The enantioselective decarboxylative protonation (EDP) of malonic or acetoacetic acid
derivatives is a synthetic methodology by which the chirality of the product is generated …

BJOC - Asymmetric organocatalytic decarboxylative Mannich reaction using β-keto acids: A
new protocol for the synthesis of chiral β-amino ketones Journal Logo Diamond Open Access …

As a result of the low reactivity of simple esters, the use of them as nucleophiles in direct
asymmetric transformations is a long‐standing challenge in synthetic organic chemistry …

An organocatalytic enantioselective decarboxylative Mannich reaction of malonic acid half
oxyesters with cyclic ketimines was developed for the preparation of enantioenriched β …

The organocatalytic enantioselective decarboxylative addition of malonic acids half
thioesters to isatins using a squaramide catalyst afforded the products with high …