Scanning electrochemical microscopy. 57. SECM tip voltammetry at different substrate potentials under quasi-steady-state and steady-state conditions

CG Zoski, CR Luman, JL Fernandez… - Analytical chemistry, 2007 - ACS Publications
We discuss SECM tip voltammetry, where a UME tip is held above a conductive substrate
within about a tip radius and a tip voltammogram is recorded as its potential is slowly …

Scanning electrochemical microscopy. Introduction and principles

AJ Bard, FRF Fan, J Kwak, O Lev - Analytical Chemistry, 1989 - ACS Publications
The technique of scanningelectrochemical microscopy (SECM) Is described. In this
technique the electrolysis current that flows as an ultramicroelectrode tip (diameter ca. 10 …

Scanning electrochemical microscopy: theory and application of the transient (chronoamperometric) SECM response

AJ Bard, G Denuault, RA Friesner… - Analytical …, 1991 - ACS Publications
Previous papers have described the theory (1-3) and ap-plications (4-12) of the scanning
electrochemical microscope (SECM) operating in the steady-state current regime. The tip …

Scanning electrochemical microscopy: preparation of submicrometer electrodes

C Lee, CJ Miller, AJ Bard - Analytical chemistry, 1991 - ACS Publications
INTRODUCTION In scanning electrochemical microscopy (SECM), a micro-voltammetric tip
electrode (eg, microdisk geometry with a tip radius of the order of micrometers) is rastered in …

Scanning electrochemical microscopy. 15. Improvements in imaging via tip-position modulation and lock-in detection

DO Wipf, AJ Bard - Analytical Chemistry, 1992 - ACS Publications
In this paper we describe tip-position modulationscanning electrochemical microscopy (TPM
SECM), a new mode of operation of the scanning electrochemical microscope (SECM) …

Scanning electrochemical microscopy. 55. Fabrication and characterization of micropipet probes

DA Walsh, JL Fernandez, J Mauzeroll… - Analytical …, 2005 - ACS Publications
The fabrication and characterization of novel micropipet probes for use in scanning
electrochemical microscopy (SECM) are described. These can be used to dispense small …

Scanning electrochemical microscopy. 46. Shielding effects on reversible and quasireversible reactions

CG Zoski, JC Aguilar, AJ Bard - Analytical chemistry, 2003 - ACS Publications
An approximate theory for the feedback mode of the scanning electrochemical microscope
(SECM) is developed to interpret the effects of substrate shielding on an ultramicroelectrode …

Scanning electrochemical microscopy 50. Kinetic study of electrode reactions by the tip generation− substrate collection mode

JL Fernandez, AJ Bard - Analytical chemistry, 2004 - ACS Publications
A scanning electrochemical microscopy (SECM) methodology for localized quantitative
kinetic studies of electrode reactions based on the tip generation− substrate collection (TG …

Scanning electrochemical microscopy. 28. Ion-selective neutral carrier-based microelectrode potentiometry

C Wei, AJ Bard, G Nagy, K Toth - Analytical Chemistry, 1995 - ACS Publications
Electrodes for scanning ion-selective potentiometric microscopy (or potentiometric SECM)
were developed and used to image local concentration profiles of NH4+, K+, and Zn2+ ions …

Scanning electrochemical microscopy. 60. Quantitative calibration of the SECM substrate generation/tip collection mode and its use for the study of the oxygen …

CM Sánchez-Sánchez, J Rodríguez-López… - Analytical …, 2008 - ACS Publications
The substrate generation/tip collection (SG/TC) mode of scanning electrochemical
microscopy (SECM) coupled with linear voltammetry is proposed as a way to quantify …