Transition-metal-catalyzed carbene transfer reactions, involving diazo compounds and their
precursors, are powerful tools for creating new C–C bonds. Depending on the involved …

The use of diazo compounds in the transition‐metal‐catalyzed coupling reactions to form C−
C and C− X (X= O, S, N, Si, P etc.) bonds have been a well established approach in organic …

The direct CH functionalization reaction is one of the most efficient strategies by which to
introduce new functional groups into small organic molecules. Over time, iron complexes …

Bioinspired, synthetic porphyrin complexes are important catalysts in organic synthesis and
play a pivotal role in efficient carbene transfer reactions. The advances in this research area …

The bis (imino) pyridine iron complex, for the first time, is developed as an effective metal
carbene catalyst for carbene transfer reactions of donor–acceptor diazo compounds. Its …

Carbenes are versatile, highly reactive intermediates with great importance in chemistry. We
recently reported on our findings on safe and scalable applications of hazardous …

Carbene transfer reactions hold a pivotal role in organic synthesis, allowing the prompt
construction of complex molecules from accessible reagents. Iron complexes emerged as …

Carbene transfer: The electron‐rich iron complex Bu 4 N [Fe (CO) 3 (NO)] efficiently
catalyzes different carbene‐transfer reactions. Various diazo compounds can be used. The …

The chemistry of metal carbene complexes has experienced an enormous development in
the past decades. Despite this fact, the use of transition metals as catalysts in reactions …

Abstract Bis (NHC) ruthenium (II)–porphyrin complexes were designed, synthesized, and
characterized. Owing to the strong donor strength of axial NHC ligands in stabilizing the …