Active sites of stoichiometric cerium oxide cations (Ce m O 2m+) probed by reactions with carbon monoxide and small hydrocarbon molecules

XN Wu, YX Zhao, W Xue, ZC Wang, SG He… - Physical Chemistry …, 2010 - pubs.rsc.org
Cerium oxide cluster cations (CemOn+, m= 2–16; n= 2m, 2m±1 and 2m±2) are prepared by
laser ablation and reacted with carbon monoxide (CO) and small hydrocarbon molecules …

Stable stoichiometry of gas-phase cerium oxide cluster ions and their reactions with CO

T Nagata, K Miyajima, F Mafuné - The Journal of Physical …, 2015 - ACS Publications
Cerium oxide cluster ions, Ce n O2 n+ x+(n= 2–9, x=− 1 to+ 2), were prepared in the gas
phase by laser ablation of a cerium oxide rod in the presence of oxygen diluted in He as the …

Experimental and Theoretical Study of the Reactions between Cerium Oxide Cluster Anions and Carbon Monoxide: Size-Dependent Reactivity of CenO2n+1 (n …

XN Wu, XL Ding, SM Bai, B Xu, SG He… - The Journal of Physical …, 2011 - ACS Publications
Reactions of cerium oxide cluster anions with carbon monoxide are investigated by time-of-
flight mass spectrometry and density functional theory computations aided with molecular …

Reactivity of oxygen deficient cerium oxide clusters with small gaseous molecules

T Nagata, K Miyajima, RA Hardy… - The Journal of …, 2015 - ACS Publications
Oxygen deficient cerium oxide cluster ions, Ce n O m+(n= 2–10, m= 1–2 n) were prepared in
the gas phase by laser ablation of a cerium oxide rod. The reactivity of the cluster ions was …

Oxidation of CO and NO on composition-selected cerium oxide cluster cations

S Hirabayashi, M Ichihashi - The Journal of Physical Chemistry A, 2013 - ACS Publications
The collisional reactions of composition-selected cerium oxide cluster cations, Ce n O m+(n=
2–6; m≤ 2 n), with CO and NO have been investigated under single collision conditions …

Cerium oxyhydroxide clusters: formation, structure, and reactivity

F Aubriet, JJ Gaumet, WA De Jong… - The Journal of …, 2009 - ACS Publications
Cerium oxyhydroxide cluster anions were produced by irradiating ceric oxide particles by
using 355 nm laser pulses that were synchronized with pulses of nitrogen gas admitted to …

[HTML][HTML] Molecular and electronic structures of cerium and cerium suboxide clusters

JO Kafader, JE Topolski, CC Jarrold - The Journal of Chemical Physics, 2016 - pubs.aip.org
The anion photoelectron (PE) spectra of Ce 2 O y−(y= 1, 2), Ce 3 O y−(y= 0–4), Ce 4 O y−(y=
0–2), and Ce 5 O y−(y= 1, 2) are reported and analyzed with supporting results from density …

Structures and vibrational spectroscopy of partially reduced gas-phase cerium oxide clusters

AM Burow, T Wende, M Sierka, R Włodarczyk… - Physical Chemistry …, 2011 - pubs.rsc.org
This work demonstrates that the most stable structures of even small gas-phase aggregates
of cerium oxide with 2–5 cerium atoms show structural motifs reminiscent of the bulk ceria …

Molybdenum oxide cluster ions in the gas phase: structure and reactivity with small molecules

EF Fialko, AV Kikhtenko, VB Goncharov… - The Journal of …, 1997 - ACS Publications
The combination of the Knudsen cell with a standard cubic ICR trapping cell produces a
number of cluster ions of molybdenum oxides Mo x O y+(x= 1− 5, y= 1− 15). Ionization of …

The CeO2+ Cation:  Gas-Phase Reactivity and Electronic Structure

C Heinemann, HH Cornehl, D Schröder… - Inorganic …, 1996 - ACS Publications
“Bare” CeO2+ ions can be prepared in the gas phase by consecutive oxidation of Ce+ with
O2 and NO2. The ability to activate saturated and unsaturated hydrocarbons is investigated …