Abstract A new series of 2, 4, 6‐triaryl‐λ5‐phosphinines have been synthesized that contain
different substituents both on the carbon backbone and the phosphorus atom of the six …

The discovery and molecular engineering of novel electroluminescent materials is still a
challenge in optoelectronics. In this work, the development of new π‐conjugated oligomers …

We report the substitution of λ5-phosphinines (2, 6-dicarbonitrile diphenyl-1-λ5-
phosphinine) with an amino group. The impact of these modifications on both the optical and …

This article presents the synthesis of a new family of naphthyl‐fused phosphepines through
Ni‐mediated C− C coupling. Interestingly, the chlorophosphine oxide intermediate shows …

A family of electroluminescent organophosphorus materials for solution-processed organic
light-emitting diodes is reported. The investigated systems present a six-membered …

The synthesis of 2, 4, 6-triphenylphosphinine has been revisited and a general protocol for
the preparation of such low-coordinate phosphorus compounds in good to excellent yields …

Phosphazenes, one of the most important classes of organophosphorus compounds
containing phosphorus (V) with double bonds between P and N, can be cyclic molecules or …

A practical synthesis of a variety of λ5-phosphinines, which show distinct fluorescence both
in solution and solid state, is described. Both C4-selective electrophilic substitutions and the …

A hitherto unprecedented electronic situation has been observed for a substituted, pyridyl-
functionalized phosphinine. In contrast to previous studies, this compound shows …

π-Extended molecules based on six-membered phosphorus heterocycles are exceptional
systems due to their unique structural and chemical properties. Even though the first six …