Stable solar-driven oxidation of water by semiconducting photoanodes protected by transparent catalytic nickel oxide films

K Sun, FH Saadi, MF Lichterman… - Proceedings of the …, 2015 - National Acad Sciences
Reactively sputtered nickel oxide (NiOx) films provide transparent, antireflective, electrically
conductive, chemically stable coatings that also are highly active electrocatalysts for the …

Protection of inorganic semiconductors for sustained, efficient photoelectrochemical water oxidation

MF Lichterman, K Sun, S Hu, X Zhou, MT McDowell… - Catalysis Today, 2016 - Elsevier
Small-band-gap (E g< 2 eV) semiconductors must be stabilized for use in integrated devices
that convert solar energy into the bonding energy of a reduced fuel, specifically H 2 (g) or a …

Stable Solar-Driven Water Oxidation to O2(g) by Ni-Oxide-Coated Silicon Photoanodes

K Sun, MT McDowell, AC Nielander, S Hu… - The journal of …, 2015 - ACS Publications
Semiconductors with small band gaps (< 2 eV) must be stabilized against corrosion or
passivation in aqueous electrolytes before such materials can be used as photoelectrodes …

p-Type transparent conducting oxide/n-type semiconductor heterojunctions for efficient and stable solar water oxidation

L Chen, J Yang, S Klaus, LJ Lee… - Journal of the …, 2015 - ACS Publications
Achieving stable operation of photoanodes used as components of solar water splitting
devices is critical to realizing the promise of this renewable energy technology. It is shown …

Sputtered NiOx films for stabilization of p+ n-InP photoanodes for solar-driven water oxidation

K Sun, Y Kuang, E Verlage, BS Brunschwig… - Advanced Energy …, 2015 - osti.gov
A reactively sputtered NiOx film has been used here to stabilize a buried-junction p+ n-InP
photoanode from anodic dissolution/corrosion for> 48 h of continuous light-driven evolution …

Stabilization of Si microwire arrays for solar-driven H 2 O oxidation to O 2 (g) in 1.0 M KOH (aq) using conformal coatings of amorphous TiO 2

MR Shaner, S Hu, K Sun, NS Lewis - Energy & Environmental Science, 2015 - pubs.rsc.org
Conductive, amorphous TiO2 coatings deposited by atomic-layer deposition, in combination
with a sputter deposited NiCrOx oxygen-evolution catalyst, have been used to protect Si …

Tin oxide as a protective heterojunction with silicon for efficient photoelectrochemical water oxidation in strongly acidic or alkaline electrolytes

IA Moreno‐Hernandez, BS Brunschwig… - Advanced Energy …, 2018 - Wiley Online Library
Photoelectrodes without ap–n junction are often limited in efficiency by charge
recombination at semiconductor surfaces and slow charge transfer to electrocatalysts. This …

Stabilization of n-cadmium telluride photoanodes for water oxidation to O 2 (g) in aqueous alkaline electrolytes using amorphous TiO 2 films formed by atomic-layer …

MF Lichterman, AI Carim, MT McDowell, S Hu… - Energy & …, 2014 - pubs.rsc.org
Although II–VI semiconductors such as CdS, CdTe, CdSe, ZnTe, and alloys thereof can have
nearly ideal band gaps and band-edge positions for the production of solar fuels, II–VI …

Nickel oxide functionalized silicon for efficient photo-oxidation of water

K Sun, N Park, Z Sun, J Zhou, J Wang… - Energy & …, 2012 - pubs.rsc.org
We report a nickel oxide (NiOx) thin film, from a cost-effective sol–gel process, coated n-type
silicon (n-Si) as a photoanode for efficient photo-oxidation of water under neutral pH …

High-performance silicon photoanodes passivated with ultrathin nickel films for water oxidation

MJ Kenney, M Gong, Y Li, JZ Wu, J Feng, M Lanza… - Science, 2013 - science.org
Silicon's sensitivity to corrosion has hindered its use in photoanode applications. We found
that deposition of a~ 2-nanometer nickel film on n-type silicon (n-Si) with its native oxide …