Scanning electrochemical microscopy: theory and experiment for the positive feedback mode with unequal diffusion coefficients of the redox mediator couple

RD Martin, PR Unwin - Journal of Electroanalytical Chemistry, 1997 - Elsevier
Theory for the chronoamperometric positive feedback mode of the scanning electrochemical
microscope (SECM) is extended to include the situation where the oxidised and reduced …

Theory and experiment for the substrate generation/tip collection mode of the scanning electrochemical microscope: application as an approach for measuring the …

RD Martin, PR Unwin - Analytical Chemistry, 1998 - ACS Publications
A numerical model for the substrate generation/tip collection (SG/TC) mode of the scanning
electrochemical microscope (SECM), with amperometric electrodes, is developed and …

Probing heterogeneous electron transfer at an unbiased conductor by scanning electrochemical microscopy in the feedback mode

H Xiong, J Guo, S Amemiya - Analytical chemistry, 2007 - ACS Publications
The theory of the feedback mode of scanning electrochemical microscopy is extended for
probing heterogeneous electron transfer at an unbiased conductor. A steady-state SECM …

Scanning electrochemical microscopy: theory and application of the transient (chronoamperometric) SECM response

AJ Bard, G Denuault, RA Friesner… - Analytical …, 1991 - ACS Publications
Previous papers have described the theory (1-3) and ap-plications (4-12) of the scanning
electrochemical microscope (SECM) operating in the steady-state current regime. The tip …

Scanning electrochemical microscopy. 46. Shielding effects on reversible and quasireversible reactions

CG Zoski, JC Aguilar, AJ Bard - Analytical chemistry, 2003 - ACS Publications
An approximate theory for the feedback mode of the scanning electrochemical microscope
(SECM) is developed to interpret the effects of substrate shielding on an ultramicroelectrode …

Scanning electrochemical microscopy Kinetics of chemical reactions following electron-transfer measured with the substrate-generation–tip-collection mode

RD Martin - Journal of the Chemical Society, Faraday Transactions, 1998 - pubs.rsc.org
The substrate-generation–tip-collection (SG–TC) mode of the scanning electrochemical
microscope (SECM) is used as a new approach to investigate the kinetics of EC processes …

Scanning electrochemical microscopy. Theory of the feedback mode for hemispherical ultramicroelectrodes: steady-state and transient behavior

Y Selzer, D Mandler - Analytical chemistry, 2000 - ACS Publications
This contribution represents the first comprehensive attempt to treat complex geometry
configurations of the scanning electrochemical microscope (SECM) using the alternating …

Scanning electrochemical microscopy. Theory of the feedback mode

J Kwak, AJ Bard - Analytical Chemistry, 1989 - ACS Publications
The steady-state current that flows between the scanning tip (a disk ultramicroelectrode
Imbedded In an Insulating sheath) and a planar sample substrate In a scanning …

Scanning electrochemical microscopy: VII. Effect of heterogeneous electron‐transfer rate at the substrate on the tip feedback current

DO Wipf, AJ Bard - Journal of the Electrochemical Society, 1991 - iopscience.iop.org
The dependence of the SECM feedback current on finite heterogeneous electron-transfer
(et) kinetics at the substrate electrode was examined by experimental studies of the …

Scanning electrochemical microscopy. 20. Steady-state measurements of the fast heterogeneous kinetics in the ferrocene/acetonitrile system

MV Mirkin, TC Richards, AJ Bard - The Journal of Physical …, 1993 - ACS Publications
The application of the scanning electrochemical microscope (SECM) for steady-state
measurements of fast heterogeneous kinetics is described. The method is based on the …