A unified new analytical approximation for negative feedback currents with a microdisk SECM tip

R Cornut, C Lefrou - Journal of Electroanalytical Chemistry, 2007 - Elsevier
Analytical approximations for steady-state negative feedback currents in scanning
electrochemical microscopy (SECM) experiments using a microdisk are discussed. A …

New analytical approximations for negative feedback currents with a microdisk SECM tip

R Cornut, C Lefrou - Journal of Electroanalytical Chemistry, 2007 - Elsevier
Analytical approximations for steady-state negative feedback currents in scanning
electrochemical microscopy (SECM) experiments using a microdisk are discussed …

A unified new analytical approximation for positive feedback currents with a microdisk SECM tip

C Lefrou - Journal of Electroanalytical Chemistry, 2006 - Elsevier
Analytical approximations for steady-state positive feedback currents in scanning
electrochemical microscopy (SECM) experiments using a microdisk are discussed. The use …

Analytical expressions for quantitative scanning electrochemical microscopy (SECM)

C Lefrou, R Cornut - ChemPhysChem, 2010 - Wiley Online Library
Scanning electrochemical microscopy (SECM), is a recent analytical technique in
electrochemistry, which was developed in the 1990s and uses microelectrodes to probe …

New analytical approximation of feedback approach curves with a microdisk SECM tip and irreversible kinetic reaction at the substrate

R Cornut, C Lefrou - Journal of Electroanalytical Chemistry, 2008 - Elsevier
Available approximate expressions used in the kinetic data treatment of (scanning
electrochemical microscopy) SECM experiments in the case of steady-state feedback …

Scanning electrochemical microscopy. Theory of the feedback mode for hemispherical ultramicroelectrodes: steady-state and transient behavior

Y Selzer, D Mandler - Analytical chemistry, 2000 - ACS Publications
This contribution represents the first comprehensive attempt to treat complex geometry
configurations of the scanning electrochemical microscope (SECM) using the alternating …

Probing heterogeneous electron transfer at an unbiased conductor by scanning electrochemical microscopy in the feedback mode

H Xiong, J Guo, S Amemiya - Analytical chemistry, 2007 - ACS Publications
The theory of the feedback mode of scanning electrochemical microscopy is extended for
probing heterogeneous electron transfer at an unbiased conductor. A steady-state SECM …

Positive and negative AC impedance feedback observed above conductive substrates under SECM conditions

PM Diakowski, AS Baranski - Electrochimica Acta, 2006 - Elsevier
A relationship between the tip response and the tip-to-substrate separation distance was
investigated under alternating current scanning electrochemical microscopy (AC-SECM) …

Simple and clear evidence for positive feedback limitation by bipolar behavior during scanning electrochemical microscopy of unbiased conductors

AI Oleinick, D Battistel, S Daniele, I Svir… - Analytical …, 2011 - ACS Publications
On the basis of an experimentally validated simple theoretical model, it is demonstrated
unambiguously that when an unbiased conductor is probed by a scanning electrochemical …

Scanning electrochemical microscopy (SECM): An investigation of the effects of tip geometry on amperometric tip response

JL Amphlett, G Denuault - The Journal of Physical Chemistry B, 1998 - ACS Publications
Transient and steady-state amperometric tip responses were simulated with an alternating
direction implicit algorithm. Compared with previous publications, the simulation domain …