A new (N‐phosphinoamidinate) manganese complex is shown to be a useful pre‐catalyst
for the hydrosilative reduction of carbonyl compounds, and in most cases at room …

We report a manganese-catalyzed hydrosilylative reduction of various primary amides to
amines (25 examples). On simple modification of the reaction conditions such as in the …

Substituted amines and their derivatives are of significant importance for the synthesis of
numerous products of the pharmaceutical and agrochemical industry. Furthermore, they …

A terminal [Ni–OH] complex 1, supported by triflamide-functionalized NHC ligands, catalyzes
the hydrosilylative reduction of a range of primary amides into primary amines in good to …

Selective reduction of esters to alcohols was accomplished through Mn (I)‐mediated
hydrosilylation reaction. The manganese tricarbonyl complex [Mn (bis‐NHC)(CO) 3Br] …

Mach′ s Dir leicht: Eine Vielzahl an Ketonen und zwei Aldehyde wurden unter milden
Bedingungen in Gegenwart des Titelkomplexes effizient hydrosilyliert (siehe Schema; R …

The cobalt carbonyl [Co2 (CO) 8] complex is employed as a useful catalyst for the reduction
of tertiary amides to the corresponding tertiary amines using 1, 1, 3, 3‐tetramethyldisiloxane …

Conspectus In recent years, interest in homogeneous manganese catalyst development has
intensified because of the earth-abundant and nontoxic nature of this metal. Although …

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Transition-metal complex-catalyzed reduction of amides with hydrosilanes: a facile
transformation of amides to amines - ScienceDirect Skip to main contentSkip to article …