Scanning electrochemical microscopy part 13. Evaluation of the tip shapes of nanometer size microelectrodes

MV Mirkin, FRF Fan, AJ Bard - Journal of Electroanalytical Chemistry, 1992 - Elsevier
The shape of steady-state current-distance (i Td) curves obtained by scanning
electrochemical microscopy (SECM) with a submicrometer conical-type tip is substantially …

Scanning electrochemical microscopy: preparation of submicrometer electrodes

C Lee, CJ Miller, AJ Bard - Analytical chemistry, 1991 - ACS Publications
INTRODUCTION In scanning electrochemical microscopy (SECM), a micro-voltammetric tip
electrode (eg, microdisk geometry with a tip radius of the order of micrometers) is rastered in …

Scanning electrochemical microscopy (SECM): An investigation of the effects of tip geometry on amperometric tip response

JL Amphlett, G Denuault - The Journal of Physical Chemistry B, 1998 - ACS Publications
Transient and steady-state amperometric tip responses were simulated with an alternating
direction implicit algorithm. Compared with previous publications, the simulation domain …

Scanning electrochemical microscopy. 41. Theory and characterization of ring electrodes

Y Lee, S Amemiya, AJ Bard - Analytical chemistry, 2001 - ACS Publications
Ring ultramicroelectrodes, which are of particular interest as probes for scanning
electrochemical microscopy (SECM), combined with near-field scanning optical microscopy …

Scanning electrochemical microscopy: VII. Effect of heterogeneous electron‐transfer rate at the substrate on the tip feedback current

DO Wipf, AJ Bard - Journal of the Electrochemical Society, 1991 - iopscience.iop.org
The dependence of the SECM feedback current on finite heterogeneous electron-transfer
(et) kinetics at the substrate electrode was examined by experimental studies of the …

Scanning electrochemical microscopy: Theory and characterization of electrodes of finite conical geometry

CG Zoski, B Liu, AJ Bard - Analytical chemistry, 2004 - ACS Publications
Finite conical electrodes, which are of particular interest as probes for imaging of surfaces
using scanning electrochemical microscopy (SECM), in kinetic studies and in probing thin …

Scanning electrochemical microscopy: theory and application of the transient (chronoamperometric) SECM response

AJ Bard, G Denuault, RA Friesner… - Analytical …, 1991 - ACS Publications
Previous papers have described the theory (1-3) and ap-plications (4-12) of the scanning
electrochemical microscope (SECM) operating in the steady-state current regime. The tip …

Fabrication of nanometer-sized electrodes and tips for scanning electrochemical microscopy

P Sun, Z Zhang, J Guo, Y Shao - Analytical Chemistry, 2001 - ACS Publications
A novel method for fabrication of nanometer-sized electrodes and tips suitable for scanning
electrochemical microscopy (SECM) is reported. A fine etched Pt wire is coated with …

Scanning electrochemical microscopy. Introduction and principles

AJ Bard, FRF Fan, J Kwak, O Lev - Analytical Chemistry, 1989 - ACS Publications
The technique of scanningelectrochemical microscopy (SECM) Is described. In this
technique the electrolysis current that flows as an ultramicroelectrode tip (diameter ca. 10 …

Scanning electrochemical microscopy. 28. Ion-selective neutral carrier-based microelectrode potentiometry

C Wei, AJ Bard, G Nagy, K Toth - Analytical Chemistry, 1995 - ACS Publications
Electrodes for scanning ion-selective potentiometric microscopy (or potentiometric SECM)
were developed and used to image local concentration profiles of NH4+, K+, and Zn2+ ions …