[HTML][HTML] Surface thermodynamics and Lewis acid-base properties of metal-organic framework Crystals by Inverse gas chromatography at infinite dilution

T Hamieh, A Jrad, T Roques-Carmes… - … of Chromatography A, 2022 - Elsevier
In this study, the surface thermodynamic properties and more particularly, the dispersive
component γ sd of the surface energy of crystals of a Zr-based MOF, UiO-66 (Zr 6 O 4 (OH) 4 …

Effect of amino functional groups on the surface properties and Lewis's acid base parameters of UiO-66 (NH2) by inverse gas chromatography

A Ali-Ahmad, T Hamieh, T Roques-Carmes, M Hmadeh… - Heliyon, 2024 - cell.com
Amino-functionalized metal organic frameworks (MOFs) have attracted much attention for
various applications such as carbon dioxide capture, water remediation and catalysis. The …

Study of acid-base interactions between some metallic oxides and model organic molecules

T Hamieh, M Nardin, M Rageul-Lescouët… - Colloids and Surfaces A …, 1997 - Elsevier
Inverse gas chromatography technique at infinite dilution was used to calculate the acidic
and basic surface characteristics of three oxides (Monogal, MgO and ZnO). We determined …

Some Irregularities in the Evaluation of Surface Parameters of Solid Materials by Inverse Gas Chromatography

T Hamieh - Langmuir, 2023 - ACS Publications
The London dispersive component of the surface energy of solid particles, their specific
interactions, and Lewis acid–base parameters were usually calculated by using the inverse …

Effect of Modulation and Functionalization of UiO-66 Type MOFs on Their Surface Thermodynamic Properties and Lewis Acid–Base Behavior

A Ali-Ahmad, T Hamieh, T Roques-Carmes, M Hmadeh… - Catalysts, 2023 - mdpi.com
In this study, we investigated the surface thermodynamic properties of four MOF structures of
the UiO-66 series, by employing seven molecular models, a thermal model, and three other …

Zeolitic imidazolate framework-methacrylate composite monolith characterization by inverse gas chromatography

K Yusuf, AY Badjah-Hadj-Ahmed, A Aqel… - … of Chromatography A, 2016 - Elsevier
Thermodynamic characterization of butyl methacrylate-co-ethylene dimethacrylate neat
monolith and zeolitic imidazolate framework-8 incorporated with butyl methacrylate-co …

Unusual chain length dependent adsorption of linear and branched alkanes on UiO-66

T Duerinck, JFM Denayer - Adsorption, 2014 - Springer
In this work, the zero coverage adsorption properties of C 5–C 10 n-and iso-alkanes on the
UiO-66, UiO-66-Me and UiO-66-NO 2 metal–organic frameworks are studied by gas phase …

New physicochemical methodology for the determination of the surface thermodynamic properties of solid particles

T Hamieh - AppliedChem, 2023 - mdpi.com
The study of the surface thermodynamic properties of solid materials is primordial for the
determination of the dispersive surface energy, polar enthalpy of adsorption and Lewis's …

Surface acid-base properties of Cu-BTC and Fe-BTC MOFs. An inverse gas chromatography and n-butylamine thermo desorption study

G Autié-Castro, E Reguera, CL Cavalcante Jr… - Inorganica Chimica …, 2020 - Elsevier
Catalytic activity is usually related to the acid-base properties of the catalyst material. Metal-
organic frameworks (MOFs) have been evaluated as potential catalysts for several reactions …

Thermodynamics of organic molecule adsorption on sorbents modified with 5-hydroxy-6-methyluracil by inverse gas chromatography

VY Gus'kov, YY Gainullina, SP Ivanov… - … of Chromatography A, 2014 - Elsevier
The thermodynamic features of organic molecule adsorption from the gaseous phase of
sorbents modified with 5-hydroxy-6-methyluracil (HMU) were studied. Molar internal energy …